Research Articles
Published 2017-03-02
Keywords
- Semi-dilute Polymer solutions,
- Couette Flow,
- compression,
- modelling,
- power law
How to Cite
Xie, D., & Dunstan, D. E. (2017). Modelling Polymers as Compressible Elastic Spheres in Couette Flow. Substantia, 1(1), 43–48. https://doi.org/10.13128/Substantia-10
Abstract
A model of polymer chains as compressible elastic spheres in flow is presented. The spherical polymer blobs are assumed to compress in simple Couette flow in accord with recent rheo-optic measurements on semi-dilute solutions. The experimentally determined decrease in radius with increasing shear rate is predicted by the model. Furthermore, the model predicts power law exponents for the viscosity-shear rate within the range of measured values for polymer chains.